Infrared and Raman Spectroscopy: Principles and Spectral InterpretationInfrared and Raman Spectroscopy: Principles and Spectral Interpretation explains the background, core principles and tests the readers understanding of the important techniques of Infrared and Raman Spectroscopy. These techniques are used by chemists, environmental scientists, forensic scientists etc to identify unknown chemicals. In the case of an organic chemist these tools are part of an armory of techniques that enable them to conclusively prove what compound they have made, which is essential for those being used in medical applications. The book reviews basic principles, instrumentation, sampling methods, quantitative analysis, origin of group frequencies and qualitative interpretation using generalized Infrared (IR) and Raman spectra. An extensive use of graphics is used to describe the basic principles of vibrational spectroscopy and the origins of group frequencies, with over 100 fully interpreted FT-IR and FT-Raman spectra included and indexed to the relevant qualitative interpretation chapter. A final chapter with forty four unknown spectra and with a corresponding answer key is included to test the readers understanding. Tables of frequencies (peaks) for both infrared and Raman spectra are provided at key points in the book and will act as a useful reference resource for those involve interpreting spectra. This book provides a solid introduction to vibrational spectroscopy with an emphasis placed upon developing critical interpretation skills. Ideal for those using and analyzing IR and Raman spectra in their laboratories as well as those using the techniques in the field.
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IR spectroscopy measures transitions between molecular vibrational energy levels as a result of the absorption of mid-IR radiation. This interaction between light and matter is a resonance condition involving the electric dipolemediated ...
... a molecule resulting in a transfer of energy. In absorption spectroscopy this will result in raising the energy of molecule from ground to a specific excited state. –. +. –. +. E Time E2 Ep () Molecular energy levels E1 Ep = E2.
In the absorption of a photon the energy of the molecule increases and DE is positive. To a first approximation, the rotational, vibrational, and electronic energies are additive: ET 1⁄4 Eel þ Evib þ Erot We are concerned with photons ...
ABSORPTION. PROCESS. The typical IR spectrometer broad band source emits all IR frequencies of interest simultaneously where the near-IR region is 14,000e4000 cmÀ1, the mid-IR region is 1/2 h ν 4000e400 cmÀ1, and the far-IR region is ...
Typical of an absorption spectroscopy, the relationship between the intensities of the incident and transmitted IR radiation and the analyte concentration is governed by the LamberteBeer law. The IR spectrum is obtained by plotting the ...
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Table des matières
1 | |
7 | |
27 | |
Chapter 4 Environmental Dependence of Vibrational Spectra | 55 |
Chapter 5 Origin of Group Frequencies | 63 |
Characteristic Group Frequencies | 73 |
Chapter 7 General Outline and Strategies for IR and Raman Spectral Interpretation | 117 |
Chapter 8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups | 135 |
Chapter 9 Unknown IR and Raman Spectra | 177 |
Appendix IR Correlation Charts | 213 |
Index | 217 |
Autres éditions - Tout afficher
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter Larkin Aucun aperçu disponible - 2017 |
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter J. Larkin Aucun aperçu disponible - 2011 |