Infrared and Raman Spectroscopy: Principles and Spectral InterpretationInfrared and Raman Spectroscopy: Principles and Spectral Interpretation explains the background, core principles and tests the readers understanding of the important techniques of Infrared and Raman Spectroscopy. These techniques are used by chemists, environmental scientists, forensic scientists etc to identify unknown chemicals. In the case of an organic chemist these tools are part of an armory of techniques that enable them to conclusively prove what compound they have made, which is essential for those being used in medical applications. The book reviews basic principles, instrumentation, sampling methods, quantitative analysis, origin of group frequencies and qualitative interpretation using generalized Infrared (IR) and Raman spectra. An extensive use of graphics is used to describe the basic principles of vibrational spectroscopy and the origins of group frequencies, with over 100 fully interpreted FT-IR and FT-Raman spectra included and indexed to the relevant qualitative interpretation chapter. A final chapter with forty four unknown spectra and with a corresponding answer key is included to test the readers understanding. Tables of frequencies (peaks) for both infrared and Raman spectra are provided at key points in the book and will act as a useful reference resource for those involve interpreting spectra. This book provides a solid introduction to vibrational spectroscopy with an emphasis placed upon developing critical interpretation skills. Ideal for those using and analyzing IR and Raman spectra in their laboratories as well as those using the techniques in the field.
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Vibrational spectroscopy includes several different techniques, the most important of which are mid-infrared (IR), near-IR, and Raman spectroscopy. Both mid-IR and Raman spectroscopy provide characteristic fundamental vibrations that ...
TABLE 1.1 Comparison of Raman, Mid-IR and Near-IR Spectroscopy Raman Infrared Near-IR Ease of sample preparation Very simple Variable Simple Liquids Very simple Very simple Very simple Powders Very simple Simple Simple Polymers Very ...
Here Xe is at the energy minimum and the force constant, K is a measure of the curvature of the potential well near Xe. From quantum mechanics we know that molecules can only exist in quantized energy states. Thus, vibrational energy is ...
The typical IR spectrometer broad band source emits all IR frequencies of interest simultaneously where the near-IR region is 14,000e4000 cmÀ1, the mid-IR region is 1/2 h ν 4000e400 cmÀ1, and the far-IR region is 400e10 cmÀ1. Typical.
Laser sources are available for excitation in the UV, visible, and near-IR spectral region (785 and 1064 nm). Thus, if visible excitation is used, the Raman scattered light will also be in the visible region.
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Table des matières
| 1 | |
| 7 | |
| 27 | |
Chapter 4 Environmental Dependence of Vibrational Spectra | 55 |
Chapter 5 Origin of Group Frequencies | 63 |
Characteristic Group Frequencies | 73 |
Chapter 7 General Outline and Strategies for IR and Raman Spectral Interpretation | 117 |
Chapter 8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups | 135 |
Chapter 9 Unknown IR and Raman Spectra | 177 |
Appendix IR Correlation Charts | 213 |
Index | 217 |
Autres éditions - Tout afficher
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter Larkin Aucun aperçu disponible - 2017 |
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter J. Larkin Aucun aperçu disponible - 2011 |
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Informations bibliographiques
| Titre | Infrared and Raman Spectroscopy: Principles and Spectral Interpretation |
| Auteur | Peter Larkin |
| Éditeur | Elsevier, 2011 |
| ISBN | 0123870186, 9780123870186 |
| Longueur | 230 pages |
| Exporter la citation | BiBTeX EndNote RefMan |