Infrared and Raman Spectroscopy: Principles and Spectral InterpretationInfrared and Raman Spectroscopy: Principles and Spectral Interpretation explains the background, core principles and tests the readers understanding of the important techniques of Infrared and Raman Spectroscopy. These techniques are used by chemists, environmental scientists, forensic scientists etc to identify unknown chemicals. In the case of an organic chemist these tools are part of an armory of techniques that enable them to conclusively prove what compound they have made, which is essential for those being used in medical applications. The book reviews basic principles, instrumentation, sampling methods, quantitative analysis, origin of group frequencies and qualitative interpretation using generalized Infrared (IR) and Raman spectra. An extensive use of graphics is used to describe the basic principles of vibrational spectroscopy and the origins of group frequencies, with over 100 fully interpreted FT-IR and FT-Raman spectra included and indexed to the relevant qualitative interpretation chapter. A final chapter with forty four unknown spectra and with a corresponding answer key is included to test the readers understanding. Tables of frequencies (peaks) for both infrared and Raman spectra are provided at key points in the book and will act as a useful reference resource for those involve interpreting spectra. This book provides a solid introduction to vibrational spectroscopy with an emphasis placed upon developing critical interpretation skills. Ideal for those using and analyzing IR and Raman spectra in their laboratories as well as those using the techniques in the field.
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Both techniques are completely complementary providing characteristic fundamental vibrations that are extensively used for the determination and identification of molecular structure. The advent of new technologies has introduced a wide ...
Vibrational spectroscopy includes several different techniques, the most important of which are mid-infrared (IR), near-IR, ... vibrations (only the higher frequency modes) and is an excellent technique for rapid, accurate quantitation.
IR spectroscopy was the first structural spectroscopic technique widely used by organic chemists. In the 1930s and 1940s both IR and Raman techniques were experimentally challenging with only a few users. However, with conceptual and ...
With the commercial availability of instrumentation, the technique then benefited from the conceptual idea of a correlation chart of important bands that concisely summarize where various functional groups can be expected to absorb.
Raman spectroscopy is well known to be a technique requiring a minimum of sample handling and preparation. Typical Raman accessories include cuvette and tube holders, solids holders, and clamps for irregular solid objects.
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Table des matières
1 | |
7 | |
27 | |
Chapter 4 Environmental Dependence of Vibrational Spectra | 55 |
Chapter 5 Origin of Group Frequencies | 63 |
Characteristic Group Frequencies | 73 |
Chapter 7 General Outline and Strategies for IR and Raman Spectral Interpretation | 117 |
Chapter 8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups | 135 |
Chapter 9 Unknown IR and Raman Spectra | 177 |
Appendix IR Correlation Charts | 213 |
Index | 217 |
Autres éditions - Tout afficher
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter Larkin Aucun aperçu disponible - 2017 |
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter J. Larkin Aucun aperçu disponible - 2011 |