Infrared and Raman Spectroscopy: Principles and Spectral InterpretationElsevier, 13 nov. 2017 - 286 pages Infrared and Raman Spectroscopy, Principles and Spectral Interpretation, Second Edition provides a solid introduction to vibrational spectroscopy with an emphasis on developing critical interpretation skills. This book fully integrates the use of both IR and Raman spectroscopy as spectral interpretation tools, enabling the user to utilize the strength of both techniques while also recognizing their weaknesses. This second edition more than doubles the amount of interpreted IR and Raman spectra standards and spectral unknowns. The chapter on characteristic group frequencies is expanded to include increased discussions of sulphur and phosphorus organics, aromatic and heteroaromatics as well as inorganic compounds. New topics include a discussion of crystal lattice vibrations (low frequency/THz), confocal Raman microscopy, spatial resolution in IR and Raman microscopy, as well as criteria for selecting Raman excitation wavelengths. These additions accommodate the growing use of vibrational spectroscopy for process analytical monitoring, nanomaterial investigations, and structural and identity determinations to an increasing user base in both industry and academia. - Integrates discussion of IR and Raman spectra - Pairs generalized IR and Raman spectra of functional groups with tables and text - Includes over 150 fully interpreted, high quality IR and Raman reference spectra - Contains fifty-four unknown IR and Raman spectra, with a corresponding answer key |
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Page 14
... 1 ) , while for the anharmonic oscillator , overtones ( Δv = ± 2 , ± 3 ) and combination bands can also result ... cm - 1 , the mid - IR region is 4000-400 cm - 1 , and the far - IR region is 400-10 cm ̄1 . Typical of an absorption ...
... 1 ) , while for the anharmonic oscillator , overtones ( Δv = ± 2 , ± 3 ) and combination bands can also result ... cm - 1 , the mid - IR region is 4000-400 cm - 1 , and the far - IR region is 400-10 cm ̄1 . Typical of an absorption ...
Page 35
Principles and Spectral Interpretation Peter Larkin. TABLE 3.1 Selected Infrared Transmitting Material Material Wave Number Range ( cm ̄1 ) Refractive Index Comments NaCl 5000-625 1.52 Common , low cost , hygroscopic KBr 5000-400 1.54 ...
Principles and Spectral Interpretation Peter Larkin. TABLE 3.1 Selected Infrared Transmitting Material Material Wave Number Range ( cm ̄1 ) Refractive Index Comments NaCl 5000-625 1.52 Common , low cost , hygroscopic KBr 5000-400 1.54 ...
Page 44
... Wave Number Range (cmL1) Refractive Index Germanium 5000e850 4.0 KRS-5 5000e275 2.38 ZnSe 5000e550 2.41 Comments Hard ... cm 1 results in a significant distortion and attenuation of the DICY nitrile band doublet at w2200 cm 1. A ...
... Wave Number Range (cmL1) Refractive Index Germanium 5000e850 4.0 KRS-5 5000e275 2.38 ZnSe 5000e550 2.41 Comments Hard ... cm 1 results in a significant distortion and attenuation of the DICY nitrile band doublet at w2200 cm 1. A ...
Page 56
... Wavenumber ( cm - 1 ) 3344 3199 2932 2858 1663 955 877 2000 1800 1600 1400 1200 1000 800 600 953 874 846 760 719 ... 400 200 Raman Shift ( cm ̄1 ) FIGURE 3.14 The FT - IR and FT - Raman spectra of the following : pure PAM and two ...
... Wavenumber ( cm - 1 ) 3344 3199 2932 2858 1663 955 877 2000 1800 1600 1400 1200 1000 800 600 953 874 846 760 719 ... 400 200 Raman Shift ( cm ̄1 ) FIGURE 3.14 The FT - IR and FT - Raman spectra of the following : pure PAM and two ...
Page 79
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Table des matières
1 | |
7 | |
4 Environmental Dependence of Vibrational Spectra | 63 |
3 Instrumentation and Sampling Methods | 85 |
7 General Outline for IR and Raman Spectral Interpretation | 135 |
8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups | 153 |
IR Correlation Charts | 261 |
9 Unknown IR and Raman Spectra | 265 |
Backcover | 277 |
Autres éditions - Tout afficher
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter Larkin Aucun aperçu disponible - 2017 |
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter J. Larkin Aucun aperçu disponible - 2011 |
Expressions et termes fréquents
400 Wavenumber cm-1 absorption Aliphatic amine Aryl Aryl CH str asym str asymmetric out-of-phase atom benzene C=O str capillary film/KBr carbon carbonyl carboxylic acid CH def CH rk CH stretch CH wag CH₂ CH3 asym def CH3 CH3 CH3 sym str characteristic bands circle str cm 1 CH3 cm 1 involving cm-¹ cm¯¹ cmL1 compounds crystalline deformation dipole Fermi resonance force constant FT-IR FT-Raman functional groups H₂O hydrogen bonding i.ph in-phase stretch in-phase symmetric in-plane Infrared Infrared and Raman inorganic intensity IR bands IR spectroscopy KBr disc laser lattice lone H methyl methylene microscope molecule near-IR Nujol Nujol mull observed olefinic oscillator out-of-phase asymmetric Pyridine Quadrant str radiation Raman scattered Raman spectra Raman spectroscopy region Ring Quad ring stretch sample preparation spectrum stretching bands stretching vibrations strong IR bands substituted sym def symmetric in-phase symmetric stretch technique trans typically vibrational spectroscopy wavelength weak