Infrared and Raman Spectroscopy: Principles and Spectral Interpretation

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Elsevier, 13 nov. 2017 - 286 pages

Infrared and Raman Spectroscopy, Principles and Spectral Interpretation, Second Edition provides a solid introduction to vibrational spectroscopy with an emphasis on developing critical interpretation skills. This book fully integrates the use of both IR and Raman spectroscopy as spectral interpretation tools, enabling the user to utilize the strength of both techniques while also recognizing their weaknesses.

This second edition more than doubles the amount of interpreted IR and Raman spectra standards and spectral unknowns. The chapter on characteristic group frequencies is expanded to include increased discussions of sulphur and phosphorus organics, aromatic and heteroaromatics as well as inorganic compounds. New topics include a discussion of crystal lattice vibrations (low frequency/THz), confocal Raman microscopy, spatial resolution in IR and Raman microscopy, as well as criteria for selecting Raman excitation wavelengths. These additions accommodate the growing use of vibrational spectroscopy for process analytical monitoring, nanomaterial investigations, and structural and identity determinations to an increasing user base in both industry and academia.

  • Integrates discussion of IR and Raman spectra
  • Pairs generalized IR and Raman spectra of functional groups with tables and text
  • Includes over 150 fully interpreted, high quality IR and Raman reference spectra
  • Contains fifty-four unknown IR and Raman spectra, with a corresponding answer key

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Page 9
... benzene. (A) Diatomic Stretch Equilibrium position of atoms Displacement Time (B) Totally symmetric CH stretch of benzene FIGURE 2.4 Normal mode of vibration for a simple diatomic such as HCl (A) and a more complex species such as ...
Page 19
... benzene and the rule of mutual exclusion holds. In a molecule with a center of symmetry, vibrations that retain the center of symmetry are IR inactive and may be Raman active. Such vibrations, as shown in Fig. 2.12, generate a change in ...
Page 20
... benzene . The Raman active symmetric stretching vibrations above are symmetric with respect to the center of symmetry . Some Infrared ( IR ) active asymmetric stretching vibrations are also shown . of this are the in - phase ( symmetric ) ...
Page 21
... benzene, 2,4,6 C-radial in-phase stretch FIGURE 2.13 Three different molecules, (A) nitrate, (B) sulfate, and (C) 1,3,5 trisubstituted benzene, 2,4,6 C-radial in-phase stretch molecules, which do not have a center of symmetry. The in ...
Page 82
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Table des matières

Infrared and Raman Spectroscopy
1
2 Basic Principles
7
4 Environmental Dependence of Vibrational Spectra
63
3 Instrumentation and Sampling Methods
85
7 General Outline for IR and Raman Spectral Interpretation
135
8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups
153
IR Correlation Charts
261
9 Unknown IR and Raman Spectra
265
Backcover
277
Droits d'auteur

Autres éditions - Tout afficher

Infrared and Raman Spectroscopy: Principles and Spectral Interpretation
Peter Larkin
Aperçu limité - 2011
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation
Peter Larkin
Aucun aperçu disponible - 2017
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation
Peter J. Larkin
Aucun aperçu disponible - 2011

Expressions et termes fréquents

400 Wavenumber cm-1 absorption Aliphatic amine Aryl Aryl CH str asym str asymmetric out-of-phase atom benzene C=O str capillary film/KBr carbon carbonyl carboxylic acid CH def CH rk CH stretch CH wag CH₂ CH3 asym def CH3 CH3 CH3 sym str characteristic bands circle str cm 1 CH3 cm 1 involving cm-¹ cm¯¹ cmL1 compounds crystalline deformation dipole Fermi resonance force constant FT-IR FT-Raman functional groups H₂O hydrogen bonding i.ph in-phase stretch in-phase symmetric in-plane Infrared Infrared and Raman inorganic intensity IR bands IR spectroscopy KBr disc laser lattice lone H methyl methylene microscope molecule near-IR Nujol Nujol mull observed olefinic oscillator out-of-phase asymmetric Pyridine Quadrant str radiation Raman scattered Raman spectra Raman spectroscopy region Ring Quad ring stretch sample preparation spectrum stretching bands stretching vibrations strong IR bands substituted sym def symmetric in-phase symmetric stretch technique trans typically vibrational spectroscopy wavelength weak

À propos de l'auteur (2017)

Peter J. Larkin leads Solvay's Spectroscopy and Materials Characterization group based in Stamford, Connecticut. He has more than 25 years of experience using IR, Raman, and NIR spectroscopy in the chemical and pharmaceutical industry. This includes managing research groups in R&D environments as well as directing analytical method development, validation, and transfer teams. He specializes in IR and Raman spectral interpretation, spectroscopic chemometric analyses, early phase API and chemical development support, and process analytical techniques (PAT). Dr. Larkin received his PhD from the University of Pittsburgh in 1990 using resonance Raman and vibrational circular dichroism spectroscopy to study heme proteins. Since that time he has worked in analytical departments both in the specialty chemical and pharmaceutical industries. While at American Cyanamid/Cytec Industries in Stamford, CT, Larkin received comprehensive training in IR interpretation from Dr. Norman B. Colthup. He subsequently worked at Wyeth Pharmaceutical, had a brief stint with Pfizer, lead the solid state analysis group at Bristol-Myers Squibb, and now leads the spectroscopy and materials characterization group at Solvay.

Informations bibliographiques

TitreInfrared and Raman Spectroscopy: Principles and Spectral Interpretation
AuteurPeter Larkin
Édition2
ÉditeurElsevier, 2017
ISBN0128042095, 9780128042090
Longueur286 pages
  
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