Infrared and Raman Spectroscopy: Principles and Spectral Interpretation

Couverture
Elsevier, 13 nov. 2017 - 286 pages

Infrared and Raman Spectroscopy, Principles and Spectral Interpretation, Second Edition provides a solid introduction to vibrational spectroscopy with an emphasis on developing critical interpretation skills. This book fully integrates the use of both IR and Raman spectroscopy as spectral interpretation tools, enabling the user to utilize the strength of both techniques while also recognizing their weaknesses.

This second edition more than doubles the amount of interpreted IR and Raman spectra standards and spectral unknowns. The chapter on characteristic group frequencies is expanded to include increased discussions of sulphur and phosphorus organics, aromatic and heteroaromatics as well as inorganic compounds. New topics include a discussion of crystal lattice vibrations (low frequency/THz), confocal Raman microscopy, spatial resolution in IR and Raman microscopy, as well as criteria for selecting Raman excitation wavelengths. These additions accommodate the growing use of vibrational spectroscopy for process analytical monitoring, nanomaterial investigations, and structural and identity determinations to an increasing user base in both industry and academia.

  • Integrates discussion of IR and Raman spectra
  • Pairs generalized IR and Raman spectra of functional groups with tables and text
  • Includes over 150 fully interpreted, high quality IR and Raman reference spectra
  • Contains fifty-four unknown IR and Raman spectra, with a corresponding answer key

À l'intérieur du livre

 

Résultats 1-5 sur 62

Page vii
... Vibrations 19 9. Selecting the Raman Excitation Wavelength 22 10. Calculating the Vibrational Spectra of Molecules ... Stretching Group (X]O, S, P, N, Si, B) 85 2. Aliphatic Groups 87 3. Conjugated Aliphatics and Aromatics 92 4 ...
Page 3
... stretch . analysis is used to reveal the presence and absence of various functional groups in the mole- cule thereby ... vibrations as simple , uncoupled oscillators ( with the exception of the cumulated double bonds ) . The actual ...
Page 4
... stretch C = C - H Arom - H C = CH2 C = CH R - CH3 Arom - CH3 R - CH2 - R R - O - CH3 R2 - N - CH3 O = C - H FIGURE 1.2 The correlation chart for CH3 , CH2 , and CH stretch infrared bands . studies of the internal vibrations of molecules ...
Page 8
... vibrations of molecules is described by the internal degrees of freedom resulting in the well - known 3n - 6 and 3n ... stretching vibration . The more complicated CO2 molecule has 3 ( 3 ) - 5 = 4 degrees of freedom and therefore ...
Page 9
... stretches include op (out-of-phase or asymmetric) and in (in-phase or symmetric). The deformation (or bending) ... vibrations for water and carbon dioxide shown in Fig. 2.3 are the normal mode of vibrations. For these vibrations ...

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Pages sélectionnées

Table des matières

Infrared and Raman Spectroscopy
1
2 Basic Principles
7
4 Environmental Dependence of Vibrational Spectra
63
3 Instrumentation and Sampling Methods
85
7 General Outline for IR and Raman Spectral Interpretation
135
8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups
153
IR Correlation Charts
261
9 Unknown IR and Raman Spectra
265
Backcover
277
Droits d'auteur

Autres éditions - Tout afficher

Infrared and Raman Spectroscopy: Principles and Spectral Interpretation
Peter Larkin
Aperçu limité - 2011
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation
Peter Larkin
Aucun aperçu disponible - 2017
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation
Peter J. Larkin
Aucun aperçu disponible - 2011

Expressions et termes fréquents

400 Wavenumber cm-1 absorption Aliphatic amine Aryl Aryl CH str asym str asymmetric out-of-phase atom benzene C=O str capillary film/KBr carbon carbonyl carboxylic acid CH def CH rk CH stretch CH wag CH₂ CH3 asym def CH3 CH3 CH3 sym str characteristic bands circle str cm 1 CH3 cm 1 involving cm-¹ cm¯¹ cmL1 compounds crystalline deformation dipole Fermi resonance force constant FT-IR FT-Raman functional groups H₂O hydrogen bonding i.ph in-phase stretch in-phase symmetric in-plane Infrared Infrared and Raman inorganic intensity IR bands IR spectroscopy KBr disc laser lattice lone H methyl methylene microscope molecule near-IR Nujol Nujol mull observed olefinic oscillator out-of-phase asymmetric Pyridine Quadrant str radiation Raman scattered Raman spectra Raman spectroscopy region Ring Quad ring stretch sample preparation spectrum stretching bands stretching vibrations strong IR bands substituted sym def symmetric in-phase symmetric stretch technique trans typically vibrational spectroscopy wavelength weak

À propos de l'auteur (2017)

Peter J. Larkin leads Solvay's Spectroscopy and Materials Characterization group based in Stamford, Connecticut. He has more than 25 years of experience using IR, Raman, and NIR spectroscopy in the chemical and pharmaceutical industry. This includes managing research groups in R&D environments as well as directing analytical method development, validation, and transfer teams. He specializes in IR and Raman spectral interpretation, spectroscopic chemometric analyses, early phase API and chemical development support, and process analytical techniques (PAT). Dr. Larkin received his PhD from the University of Pittsburgh in 1990 using resonance Raman and vibrational circular dichroism spectroscopy to study heme proteins. Since that time he has worked in analytical departments both in the specialty chemical and pharmaceutical industries. While at American Cyanamid/Cytec Industries in Stamford, CT, Larkin received comprehensive training in IR interpretation from Dr. Norman B. Colthup. He subsequently worked at Wyeth Pharmaceutical, had a brief stint with Pfizer, lead the solid state analysis group at Bristol-Myers Squibb, and now leads the spectroscopy and materials characterization group at Solvay.

Informations bibliographiques

TitreInfrared and Raman Spectroscopy: Principles and Spectral Interpretation
AuteurPeter Larkin
Édition2
ÉditeurElsevier, 2017
ISBN0128042095, 9780128042090
Longueur286 pages
  
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