Infrared and Raman Spectroscopy: Principles and Spectral InterpretationElsevier, 13 juil. 2011 - 230 pages Infrared and Raman Spectroscopy: Principles and Spectral Interpretation explains the background, core principles and tests the readers understanding of the important techniques of Infrared and Raman Spectroscopy. These techniques are used by chemists, environmental scientists, forensic scientists etc to identify unknown chemicals. In the case of an organic chemist these tools are part of an armory of techniques that enable them to conclusively prove what compound they have made, which is essential for those being used in medical applications. The book reviews basic principles, instrumentation, sampling methods, quantitative analysis, origin of group frequencies and qualitative interpretation using generalized Infrared (IR) and Raman spectra. An extensive use of graphics is used to describe the basic principles of vibrational spectroscopy and the origins of group frequencies, with over 100 fully interpreted FT-IR and FT-Raman spectra included and indexed to the relevant qualitative interpretation chapter. A final chapter with forty four unknown spectra and with a corresponding answer key is included to test the readers understanding. Tables of frequencies (peaks) for both infrared and Raman spectra are provided at key points in the book and will act as a useful reference resource for those involve interpreting spectra. This book provides a solid introduction to vibrational spectroscopy with an emphasis placed upon developing critical interpretation skills. Ideal for those using and analyzing IR and Raman spectra in their laboratories as well as those using the techniques in the field.
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À l'intérieur du livre
Résultats 6-10 sur 89
... bands to be observed, the molecular vibration must cause a change in the polarizability. Both Rayleigh and Raman are two photon processes involving scattering of incident light ðhcnLÞ, from a “virtual state.” The incident photon is ...
... SPECTRA. OF. MOLECULES. The basis of much of the current understanding of molecular vibrations and the localized group vibrations that give rise to useful group frequencies observed in the IR and Raman spectra of molecules is based upon ...
... frequencies and intensities to insure reliable assignments of experimentally observed vibrational bands. The ab initio Hartree-Fock (HF) method is an older quantum mechanical based approach.9,10 The HF methodology neglects the mutual ...
... IR spectrum. The single beam background spectrum provides a wavelength ... IR region. For FT-Raman spectrometers, the source depicted in Fig. 3.4 is the Raman ... bands due to XeH type bonds in the near-IR spectral region which can ...
... IR spectrum and a so-called false spectrum. A broadening of the most intense bands and a strengthening of the weak bands characterize false IR spectra. In general, this is caused by a non-uniform sample film or distribution of sample in ...
Table des matières
1 | |
7 | |
27 | |
Chapter 4 Environmental Dependence of Vibrational Spectra | 55 |
Chapter 5 Origin of Group Frequencies | 63 |
Characteristic Group Frequencies | 73 |
Chapter 7 General Outline and Strategies for IR and Raman Spectral Interpretation | 117 |
Chapter 8 Illustrated IR and Raman Spectra Demonstrating Important Functional Groups | 135 |
Chapter 9 Unknown IR and Raman Spectra | 177 |
Appendix IR Correlation Charts | 213 |
Index | 217 |
Autres éditions - Tout afficher
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter Larkin Aucun aperçu disponible - 2017 |
Infrared and Raman Spectroscopy: Principles and Spectral Interpretation Peter J. Larkin Aucun aperçu disponible - 2011 |